@techreport {1372, title = {Energy Performance Analysis of Electrochromic Windows in New York Commercial Office Buildings}, year = {2002}, month = {11/2002}, abstract = {

A DOE-2.1E energy simulation analysis of a switchable electrochromic (EC) glazing with daylighting controls has been conducted for prototypical office buildings in New York (NY). The modeling included four types of office buildings: "old" and "new" vintages and large (10,405 m2, 112,000 ft2) and small (502m2, 5400 ft2) buildings. Five commercially available, base case windows with and without interior shades were modeled. Window area varied from 0 to 60\% of the exterior floor-to-floor wall area. The electric lighting had either no controls or continuous daylighting controls. The prototypes were modeled in New York City or Buffalo.

Energy performance ata are given for each of the four perimeter zones. Data are presented as a function of window-to-wall ratio in order to better understand the interactions between 1) electric lighting energy use and daylight admission and 2) solar heat gains and space-conditioning energy use. Maximum and minimum reductions in energy use between the EC glazing and all other base case conditions are also presented. Projected energy use reductions relative to typical specified NY office buildings are presented as an indication of the potential impacts EC glazings might have in retrofit and new construction.

The energy and demand reductions provided by EC glazings with daylighting controls relative to what is typically specified in office buildings in NY are quite substantial. EC glazings will also dampen fluctuations in interior daylight levels and window brightness, potentially increasing visual comfort.

}, author = {Eleanor S. Lee and L. Zhou and Mehry Yazdanian and Vorapat Inkarojrit and Jonathan L. Slack and Michael D. Rubin and Stephen E. Selkowitz} } @conference {11799, title = {Electrochromism in Copper Oxide Thin Films}, booktitle = {4th International Meeting on Electrochromism}, year = {2000}, month = {08/2000}, address = {Uppsala, Sweden}, abstract = {

Transparent thin films of copper(I) oxide prepared on conductive SnO2:F glass substrates by anodic oxidation of sputtered copper films or by direct electrodeposition of Cu2O transformed reversibly to opaque metallic copper films when reduced in alkaline electrolyte. In addition, the same Cu2O films transform reversibly to black copper(II) oxide when cycled at more anodic potentials. Copper oxide-to-copper switching covered a large dynamic range, from 85\% and 10\% photopic transmittance, with a coloration efficiency of about 32 cm2/C. Gradual deterioration of the switching range occurred over 20 to 100 cycles. This is tentatively ascribed to coarsening of the film and contact degradation caused by the 65\% volume change on conversion of Cu to Cu2O. Switching between the two copper oxides (which have similar volumes) was more stable and more efficient (CE = 60 cm2/C), but covered a smaller transmittance range (60\% to 44\% T). Due to their large electrochemical storage capacity and tolerance for alkaline electrolytes, these cathodically coloring films may be useful as counter electrodes for anodically coloring electrode films such as nickel oxide or metal hydrides.

}, author = {Thomas J. Richardson and Jonathan L. Slack and Michael D. Rubin} } @article {11859, title = {Evaluation of the Plasma Distribution of a Quasi-Linear Constricted Plasma Source}, journal = {IEEE Transactions on Plasma Science}, volume = {27}, number = {1}, year = {1999}, month = {02/1999}, pages = {82-83}, chapter = {82}, abstract = {

The quasi-linear constricted plasma source is a downstream plasma source with ten linearly aligned discharge cells. Each cell operates on the basis of a constricted glow discharge. The plasma output can easily be monitored by the plasma-emitted light. The information is not only intuitive but can also be used to operate on-line feedback control of the plasma source which is important for large-area plasma processing of materials.

}, keywords = {Constricted plasma source, gas plasma flow, plasma diagnostics, plasma processing of materials}, author = {Andr{\'e} Anders and Robert A. MacGill and Michael D. Rubin} } @article {11766, title = {Effect of Hydrogen Insertion on the Optical Properties of PD-Coated Magnesium Lanthanides}, journal = {Electrochimica Acta}, year = {1998}, month = {9/1998}, address = {London, U.K.}, abstract = {

Metallic magnesium lanthanide thin films upon insertion of hydrogen transform to a highly transparent hydride phase. With a Pd overlayer, the transformation can be produced either by electrochemical insertion of hydrogen or by exposing the film to hydrogen gas. Unlike amorphous oxide electrochromics, the transformation is accompanied by a large change in visible reflectance (about 50\%). The optical switching effect in these materials is investigated in terms of changes in the complex refractive index as determined by variable-angle spectroscopic ellipsometric and normal-incidence radiometric measurements over the solar spectrum. Furthermore the optical effect of converting the Pd caplayer to Pd-H was determined. It is shown that the pd layer limits the visible transmittance of the hyrdrided stack to about 35-40\%. Whereas the extinction coefficient of the dehydrided LnMg-layers at 550 nm is between 2.2 and 3.1, it is as low as 10-4 in the transparent state.

}, author = {Klaus von Rottkay and Michael D. Rubin and Franck Michalak and Robert D. Armitage and Thomas J. Richardson and Jonathan L. Slack and Peter A. Duine} } @article {11792, title = {Electrochromic lithium nickel oxide by pulsed laser deposition and sputtering}, journal = {Solar Energy Materials and Solar Cells}, volume = {54}, number = {4-Jan}, year = {1998}, month = {07/1998}, pages = {59-66}, chapter = {59}, abstract = {

Thin films of lithium nickel oxide were deposited by sputtering and pulsed laser deposition (PLD) from targets of pressed LiNiO2 powder. The composition and structure of these films were analyzed using a variety of techniques, such as nuclear-reaction analysis, Rutherford backscattering spectrometry (RBS), X-ray diffraction, infrared spectroscopy, and atomic-force microscopy. Crystalline structure, surface morphology and chemical composition of LixNi1-xO thin films depend strongly on deposition oxygen pressure, temperature as well as substrate{\textendash}target distance. The films produced at temperatures lower than 600{\textdegree}C spontaneously absorb CO2 and H2O at their surface once they are exposed to the air. The films deposited at 600{\textdegree}C proved to be stable in air over a long period. Even at room temperature the PLD films are denser and more stable than sputtered films. RBS determined the composition of the best films to be Li0.5Ni0.5O deposited by PLD at 60\ mTorr O2 pressure. Electrochemical tests show that the films exhibit excellent reversibility in the range 1.0{\textendash}3.4\ V versus lithium. Electrochemical formatting which is used to develop electrochromism in other films is not needed for the stoichiometric films. The optical transmission range is almost 70\% at 550\ nm for 150\ nm-thick films. Devices made from these films were analyzed using novel reference electrodes and by disassembling after cycling.

}, keywords = {Lithium nickel oxide, pulsed laser deposition, sputtering}, doi = {10.1016/S0927-0248(97)00223-7}, author = {Michael D. Rubin and Shi-Jie Wen and Thomas J. Richardson and John B. Kerr and Klaus von Rottkay and Jonathan L. Slack} } @article {11794, title = {Electrochromic Lithium Nickel Oxide Thin Films by RF-Sputtering from a LiNiO2 Target}, journal = {Electrochimica Acta}, volume = {44}, number = {18}, year = {1998}, pages = {3085-3092}, abstract = {

Thin films of lithium nickel oxide were deposited by rf sputtering from a stoichiometric LiNiO2 target. The composition and structure of these films depended on the oxygen pressure during deposition (sputtering gas is Argon), and, to a certain extent, the target history. The sputtering geometry, i.e. the substrate to target distance and the sputtering angle were also critical. the films exhibit excellent reversibility in the potential range 1.1V to 3.8 V vs Li/Li+ and could be cycled in a liquid electrolyte half cell for more than 3000 cycles with a switching range ΔTvis close to 70\%. The coloration efficiency in the visible was typically -30 to -40 cm2 C-1. The switching performance of a device utilizing a lithium nickel oxide film as counter electrode for a tungsten oxide electrochromic film is reported.

}, author = {Franck Michalak and Klaus von Rottkay and Thomas J. Richardson and Jonathan L. Slack and Michael D. Rubin} } @article {11805, title = {Ellipsometry on Sputter Deposited Tin Oxide Films: Optical Constants Versus Stoichiometry Hydrogen Content, and Amount of Electrochemically Intercalated Lithium}, journal = {Applied Optics}, volume = {37}, number = {31}, year = {1998}, pages = {7734-7741}, abstract = {

Tin oxide thin films were deposited by reactive radio-frequency magnetron sputtering onto In2O3:Sn coated and bare glass substrates. Optical constants in the 300-2500 nm wavelength range were determined by a combination of variable-angle spectroscopic ellipsometry and spectrophotometric transmittance measurements. Surface roughness was modeled from optical measurements and compared with atomic-force microscopy. The two techniques gave consistent results. The fit between experimental optical data and model results could be significantly improved when it was assumed that the refractive index of the Sn oxide varied across the film thickness. Varying the oxygen partial pressure during deposition made it possible to obtain films whose complex refractive index changed at the transition from SnO to SnO2. An addition of hydrogen gas during sputtering led to lower optical constants in the full spectral range in connection with a blue shift of the band gap. Electrochemical intercalation of lithium ions into the Sn oxide films raised their refractive index and enhanced their refractive-index gradient.

}, author = {Jan Isidorsson and Claes G. Granqvist and Klaus von Rottkay and Michael D. Rubin} } @conference {11809, title = {Energy and Daylight Performance of Angular Selective Glazings}, booktitle = {ASHRAE/DOE/BTECC Conference, Thermal Performance of the Exterior Envelopes of Buildings VII}, year = {1998}, month = {12/1998}, address = {Clearwater Beach, FL}, abstract = {

This paper presents the results of a study investigating the energy and daylight performance of anisotropic angular selective glazings. The DOE-2.1E energy simulation program was used to determine the annual cooling, lighting and total electricity use, and peak electric demand. RADIANCE, a lighting simulation program, was used to determine daylight illuminance levels and distribution. We simulated a prototypical commercial office building module located in Blythe, California. We chose three hypothetical conventional windows for comparison: a single-pane tinted window, a double-pane low-E window, and a double-pane spectrally selective window. Daylighting controls were used. No interior shades were modeled in order to isolate the energy effects of the angular selective glazing. Our results show that the energy performance of the prototype angular selective windows is about the same as conventional windows for a 9.14 m (30 ft) deep south-facing perimeter zone with a large-area window in the hot, sunny climate of Blythe. It is theoretically possible to tune the angular selectivity of the glazing to achieve annual cooling energy reductions of 18\%, total electricity use reductions of 15\%, and peak electric demand reductions of 11\% when compared to a conventional glazing with the same solar-optical properties at normal incidence. Angular selective glazings can provide more uniformly distributed daylight, particularly in the area next to the window, which will result in a more visually comfortable work environment.

}, author = {Robert Sullivan and Liliana O. Beltran and Eleanor S. Lee and Michael D. Rubin and Stephen E. Selkowitz} } @conference {11778, title = {Effective Medium Approximation of the Optical properties of electrochromic cerium-titanium oxide compounds}, booktitle = {SPIE Proceedings}, volume = {3138}, year = {1997}, month = {07/1997}, pages = {19-Sep}, address = {San Diego, CA}, abstract = {

Cerium titanium oxide samples derived from a solution have been compared against sputtered films over a wide range of different compositions. X-ray diffraction was used to investigate the structural properties of the compound material existing in a two-phase mixture MAO2-MBO2. The optical properties were evaluated over the whole solar spectrum by variable angle spectroscopic ellipsometry combined with spectrophutometry. The spectral complex refractive index was determined for CeO2 and TiO2, as well as for their compounds. To reduce the large number of permutations in composition of multi-component oxides it would be useful to be able to predict the properties of the mixtures from the pure oxide components. Therefore these results were compared to those obtained by effective medium theory utilizing the optical constants of CeO2 and TiO2. In order to investigate the performance as passive counter-electrode in Li+ based electrochromic devices the films were tested by cyclic voltammetry with in-situ transmission control. Chemical composition was measured by Rutherford backscattering spectrometry. Surface morphology was analyzed by atomic force microscopy.

}, keywords = {cerium titanium oxide, effective medium theory, electrochromic, optical constants}, author = {Klaus von Rottkay and Thomas J. Richardson and Michael D. Rubin and Jonathan L. Slack} } @conference {11793, title = {Electrochromic Lithium Nickel Oxide Thin Film by Pulsed Laser Deposition}, booktitle = {Electrochemical Society Meeting}, volume = {96-24}, year = {1996}, month = {10/1996}, pages = {54-63}, address = {San Antonio, TX}, abstract = {

Thin films of lithium nickel oxide were deposited by pulsed laser deposition (PLD) from targets of pressed LiNiO2 powder with layered structure. The composition, structure and surface air sensitivity of these films were analyzed using a variety of techniques, such as nuclear reaction analysis, Rutherford backscattering spectrometry (RBS), x-ray diffraction, infrared spectroscopy, and atomic force microscopy. Optical properties were measured using a combination of variable angle spectroscopic ellipsometry and spectroradiometry. Crystalline structure, surface morphology and chemical composition of LixNi1-xO thin films depend strongly on deposition oxygen pressure, temperature as well as substrate target distance. The films produced at temperatures lower than 600 {\textdegree}C spontaneously absorb CO2 and H2O at their surface once they are exposed to the air. The films deposited at 600 {\textdegree}C proved to be stable in air over a long period. Even when deposited at room temperature the PLD films are denser and more stable than sputtered films. RBS determined that the best electrochromic films had the stoichiometric composition Li0.5Ni0.5O when deposited at 60 mTorr O2 pressure. Electrochemical tests show that the films exhibit excellent reversibility in the range 1.0 V to 3.4 V versus lithium and long cyclic life stability in a liquid electrolyte half cell. Electrochemical formatting which is used to develop electrochromism in other films and nickel oxide films is not needed for these stoichiometric films. The optical transmission range is almost 70\% at 550 nm for 120 nm thick films.

}, author = {Shi-Jie Wen and Klaus von Rottkay and Michael D. Rubin} } @conference {11828, title = {Energy Performance Analysis of Prototype Electrochromic Windows}, booktitle = {ASHRAE Transactions}, volume = {103, Part 2}, year = {1996}, month = {07/1997}, pages = {149-156}, address = {Boston, MA}, abstract = {

This paper presents the results of a study investigating the energy performance of three newly developed prototype electrochromic devices. The DOE-2.1E energy simulation program was used to analyze the annual cooling, lighting, and total electric energy use and peak demand as a function of window type and size. We simulated a prototypical commercial office building module located in the cooling-dominated locations of Phoenix, AZ and Miami, FL. Heating energy use was also studied in the heating-dominated location of Madison, WI. Daylight illuminance was used to control electrochromic state-switching. Two types of window systems were analyzed; i.e., the outer pane electrochromic glazing was combined with either a conventional low-E or a spectrally selective inner pane. The properties of the electrochromic glazings are based on measured data of new prototypes developed as part of a cooperative DOE-industry program.

Our results show the largest difference in annual electric energy performance between the different window types occurs in Phoenix and is about 6.5 kWh/m2 floor area (0.60 kWh/ft2) which can represent a cost of about $.52/m2 ($.05/ft2) using electricity costing $.08/kWh. Much larger differences exist when electrochromic windows are compared to conventional glazings in use today. At large window sizes, such energy savings can be as large as 90 kWh/m2 (8.4 kWh/ft2). Specific electrochromic performance varies with window-to-wall area ratio; i.e., at low ratios, one type electrochromic performs best, while at large ratios, another type performs best. In general, an electrochromic glazing combined with a spectrally selective glazings is better than one combined with a low-E glazing; however, at low-window-to-wall area ratios, this situation reverses slightly. There is almost no difference in peak electric demand for the different electrochromic windows analyzed.

In heating-dominated locations, the electrochromic should be maintained in its bleached state during the heating season to take advantage of beneficial solar heat gain which would reduce the amount of required heating. This also means that the electrochromic window with the largest solar heat gain coefficient is best. The largest heating energy performance difference in Madison for the various window types is 43 MJ/m2 floor area (4.0 kBtu/ft2). This represents a cost of about $.26/m2 floor area ($.024/ft2) using gas costing $0.60/therm ($5.69/GJ, $6.00/MBtu). However, a non-switching electrochromic will not provide desired glare control so that a control strategy that minimizes winter heating use may not be routinely desirable in many buildings.

}, author = {Robert Sullivan and Michael D. Rubin and Stephen E. Selkowitz} } @conference {11831, title = {The Energy Performance of Electrochromic Windows in Heating-Dominated Geographic Locations}, booktitle = {SPIE International Symposium on Optical Materials Technology for Energy Efficiency \& Solar Energy Conversion XV}, year = {1996}, month = {09/1996}, address = {Freiburg, Germany}, abstract = {

This paper presents the results of a study investigating the energy performance of electrochromic windows in heating-dominated geographic locations under a variety of state-switching control strategies. We used the DOE-2.1E energy simulation program to analyze the annual heating, cooling and lighting energy use and performance as a function of glazing type, size, and electrochromic control strategy. We simulated a prototypical commercial office building module located in Madison, Wisconsin. Control strategies analyzed were based on daylight illuminance, incident total solar radiation, and space cooling load. Our results show that overall energy performance is best if the electrochromic is left in its clear or bleached state during the heating season, but controlled during the cooling season using daylight illuminance as a control strategy. Even in such heating dominated locations as Madison, there is still a well-defined cooling season when electrochromic switching will be beneficial. However, having the electrochromic remain in its bleached state during the winter season may result in glare and visual comfort problems for occupants much in the same way as conventional glazings.

}, author = {Robert Sullivan and Eleanor S. Lee and Michael D. Rubin and Stephen E. Selkowitz} } @conference {11772, title = {Effect of Switching Control Strategies on the Energy Performance of Electrochromic Windows}, booktitle = {SPIE International Symposium on Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XIII, April 18-22, 1994}, year = {1994}, month = {04/1994}, address = {Freiburg, Germany}, abstract = {

This paper presents the results of a study investigating the energy performance of electrochromic windows under a variety of state-switching control strategies. We used the DOE-2.1E energy simulation program to analyze the annual cooling, lighting, and total electricity use and peak demand as a function of glazing type, size, and electrochromic control strategy. We simulated a prototypical commercial office building module located in the cooling-dominated location of Blythe, California. Control strategies analyzed were based on daylight illuminance, incident total solar radiation, and space cooling load. Our results show that when a daylighting strategy is used to reduce electric lighting requirements, control algorithms based on daylight illuminance results in the best overall annual energy performance. If daylighting is not an design option, controls based on space cooling load yield the best performance through solar heat gain reduction. The performance of incident total solar radiation control strategies varies as a function of the switching setpoints; for small to moderate window sizes which result in small to moderate solar gains, a large setpoint-range was best since it provides increased illuminance for daylighting without much cooling penalty; for larger window sizes, which provide adequate daylight, a smaller setpoint-range was best to reduce unwanted solar heat gains and the consequential increased cooling requirement. Of particular importance is the fact that reduction in peak electric demand was found to be independent of the type of control strategy used for electrochromic switching. This is because the electrochromics are generally in their most colored state under peak conditions, and the mechanism used for achieving such a state is not important.

}, author = {Robert Sullivan and Eleanor S. Lee and Konstantinos M. Papamichael and Michael D. Rubin and Stephen E. Selkowitz} } @techreport {1379, title = {The Energy Performance of Prototype Holographic Glazings}, year = {1993}, month = {02/1993}, abstract = {

We report on the simulation of the energy performance of prototype holographic glazings in commercial office buildings in a California climate. These prototype glazings, installed above conventional side windows, are designed to diffract the transmitted solar radiation and reflect it off the ceiling, providing adequate daylight illumination for typical office tasks up to 10m from the window. In this study, we experimentally determined a comprehensive set of solar-optical properties and characterized the contribution of the prototype holographic glazings to workplane illuminance in a scale model of a typical office space. We then used the scale model measurements to simulate the energy performance of the holographic glazings over the course of an entire year for four window orientations (North, East, South and West) for the inland Los Angeles climate, using the DOE-2.lD building energy analysis computer program. The results of our experimental analyses indicate that these prototype holographic glazings diffract only a small fraction of the incident light. The results of this study indicate that these prototype holographic glazings will not save energy in commercial office buildings. Their performance is very similar to that of clear glass, which, through side windows, cannot efficiently illuminate more than a 4m - 6m depth of a building{\textquoteleft}s perimeter, because the cooling penalties due to solar heat gain are greater than the electric lighting savings due to daylighting.

}, author = {Konstantinos M. Papamichael and Liliana O. Beltran and Reto A. Furler and Eleanor S. Lee and Stephen E. Selkowitz and Michael D. Rubin} }