@article {58221, title = {Optical characterization of fritted glass for architectural applications}, journal = {Optical Materials}, volume = {31}, year = {2009}, month = {4/2009}, pages = {949 - 958}, abstract = {

Fritted glass is commonly used as a light diffusing element in modern buildings. Traditionally it has been used for aesthetic purposes but it can also be used for energy savings by incorporating it in novel daylighting systems? To answer such questions the light scattering properties must be properly characterized.

This paper contains measurements of different varieties of fritted glass, ranging from the simplest direct-hemispherical measurements to angle-resolved goniometer measurements. Modeling the light scattering to obtain the full bidirectional scattering distribution function (BSDF) extends the measured data, making it useful in simulation programs such as Window 6 and Radiance. Surface profilometry results and SEM micrographs are included to demonstrate the surface properties of the samples studied.

}, keywords = {BRDF, BTDF, Fritted glass, Integrating sphere, light scattering}, issn = {09253467}, doi = {10.1016/j.optmat.2008.10.050}, author = {Jacob C. Jonsson and Michael D. Rubin and Annica M. Nilsson and Andreas Jonsson and Arne Roos} } @article {12123, title = {Observation of Ti4+ ions in a high power impulse magnetron sputtering plasma}, journal = {Applied Physics Letters}, volume = {93}, year = {2008}, month = {08/2008}, pages = {71504}, abstract = {

Multiply charged titanium ions including Ti4+ were observed in high power impulse magnetron sputtering discharges. Mass/charge spectrometry was used to identify metal ion species. Quadruply charged titanium ions were identified by isotope-induced broadening at mass/charge 12. Due to their high potential energy, Ti4+ ions give a high yield of secondary electrons, which in turn are likely to be responsible for the generation of multiply charged states.

}, doi = {10.1063/1.2973179}, author = {Joakim Andersson and Arutiun P. Ehiasarian and Andr{\'e} Anders} } @article {12126, title = {Obtaining the Bidirectional Transfer Distribution Function of Isotropically Scattering Materials Using an Integrating Sphere}, journal = {Optics Communications}, volume = {277}, year = {2007}, pages = {228-236}, abstract = {

This paper demonstrates a method to determine the bidirectional transfer distribution function (BTDF) using an integrating sphere. Information about the sample{\textquoteright}s angle dependent scattering is obtained by making transmittance measurements with the sample at different distances from the integrating sphere. Knowledge about the illuminated area of the sample and the geometry of the sphere port in combination with the measured data combines to an system of equations that includes the angle dependent transmittance. The resulting system of equations is an ill-posed problem which rarely gives a physical solution. A solvable system is obtained by using Tikhonov regularization on the ill-posed problem. The solution to this system can then be used to obtain the BTDF. Four bulk-scattering samples were characterised using both two goniophotometers and the described method to verify the validity of the new method. The agreement shown is great for the more diffuse samples. The solution to the low-scattering samples contains unphysical oscillations, but still gives the correct shape of the solution. The origin of the oscillations and why they are more prominent in low-scattering samples are discussed.

}, author = {Jacob C. Jonsson and Henrik Branden} } @article {12122, title = {Observation of Self-Sputtering in Energetic Condensation of Metal Ions}, journal = {Applied Physics Letters}, volume = {85}, number = {25}, year = {2004}, pages = {6137-6139}, abstract = {

The condensation of energetic metal ions on a surface may cause self-sputtering even in the absence of substrate bias. Charge-state-averaged self-sputtering yields were determined for both zirconium and gold ions generated by a cathodic vacuum arc. Films were deposited on differently biased substrates exposed to streaming Zr and Au vacuum arc plasma. The self-sputtering yields for both metals were estimated to be about 0.05 in the absence of bias, and exceeding 0.5 when bias reached - 50 V. These surprisingly high values can be reconciled with binary collision theory and molecular dynamics calculations taking high the kinetic and potential energy of vacuum arc ions into account.

}, author = {Andr{\'e} Anders} } @techreport {1701, title = {Optics Version 5.1.01}, year = {2002}, month = {11/2002}, institution = {Regents of the University of California}, address = {Berkeley, CA}, author = {Richard Versluis and Rebecca Powles and Michael D. Rubin} } @conference {12153, title = {Optical Properties of Glazing Materials at Normal Incidence}, booktitle = {Revista della Statzione Sperimentale del Vetro}, year = {2000}, month = {10/2000}, pages = {13-16}, address = {Paris, France}, abstract = {

Measurements of spectral transmittance T and reflectance R at normal incidence continue to be the most common and accurate source of energy performance data for glazing materials. Prediction of these radiometric properties from more fundamental materials data is often confounded by the complexity and uncertainty of coating structures. Angle-dependent radiometric properties of coated glazing will probably be predicted from normal-incidence data rather than being measured at many angles. The general error level demonstrated in round-robin tests is on the order 1-2\%; it is often necessary to achieve better levels of performance. Based on results obtained following the round-robin tests, it is expected that accuracy of better than 0.5\% can be generally achieved. A new type of absolute standard reference is described and tested with promising results.

}, author = {Michael D. Rubin and Rebecca Powles} } @article {1675, title = {Office Worker Response to an Automated Venetian Blind and Electric Lighting System: A Pilot Study}, journal = {Energy and Buildings}, volume = {28}, year = {1998}, month = {10/1998}, pages = {205-218}, chapter = {205}, abstract = {

A prototype integrated, dynamic building envelope and lighting system designed to optimize daylight admission and solar heat gain rejection on a real-time basis in a commercial office building is evaluated. Office worker response to the system and occupant-based modifications to the control system are investigated to determine if the design and operation of the prototype system can be improved. Key findings from the study are: (1) the prototype integrated envelope and lighting system is ready for field testing, (2) most office workers (N=14) were satisfied with the system, and (3) there were few complaints. Additional studies are needed to explain how illuminance distribution, lighting quality, and room design can affect workplane illuminance preferences.

}, keywords = {behavior, Comfort, commercial buildings, daylighting, envelope}, doi = {10.1016/S0378-7788(98)00023-1}, author = {Edward L. Vine and Eleanor S. Lee and Robert D. Clear and Dennis L. DiBartolomeo and Stephen E. Selkowitz} } @article {12144, title = {Optical Constants of Sputter-Deposited Ti-Ce Oxide and Zr-Ce Oxide Films}, journal = {Applied Optics}, volume = {37}, number = {25}, year = {1998}, month = {09/1998}, pages = {5993-6001}, chapter = {5993}, abstract = {

Films of Ti oxide, Zr oxide, Ce oxide, Ti-Ce oxide, and Zr-Ce oxide were made by means of reactive dc magnetron sputtering in a multitarget arrangement. The films were characterized by x-ray diffraction and electrochemical measurements, both techniques being firmly connected to stoichiometric information. The optical constants n and k were evalued from spectrophotometry and from variable-angle spectroscopic ellipsometry. The two analyses gave consistent results. It was found that n for the mixed-oxide films varied smoothly between the values for the pure oxides, whereas k in the band-gap range showed characteristic differences between Ti-Ce oxide and Zr-Ce oxide. It is speculated that this difference is associated with structural effects.

}, doi = {10.1364/AO.37.005993}, author = {Monica Veszelei and Lisen Kullman and Claes G. Granqvist and Klaus von Rottkay and Michael D. Rubin} } @techreport {58561, title = {Optical and Electrochromic Properties of Sol-Gel Deposited Doped Tungsten Oxide Films}, year = {1996}, month = {01/1996}, address = {Berkeley}, abstract = {

The goal of this study is to investigate the effects of doping of tungsten oxide on its electrochromic properties. The work is directed toward the development of neutral coloring tungsten oxide materials with properties superior to undoped tungsten oxide. Two basic types of sol-gel formulations were used for experimentation. Type 1 used a WOCl4 precursor. Type 2 used a proprietary (Donnelly) tungsten complex precursor. The Type 2 precursor was used only for comparison to Type 1. Doping experiments were performed using the Type 1 chemistry. The dopants studied were Co, Cr, Nb, Ti, V and Y. The range of dopant was 1-12 mole \%. Improved electrochromic behavior was observed for tungsten oxide films doped with V and Ti.

Analysis of the films included x-ray diffraction, ellipsometry, cyclic voltammetry and spectrophotometry. X-ray diffraction showed that all films heat treated at temperatures below 300{\textdegree}C were amorphous in structure. The refractive indices for undoped films were measured. We found the n, k values of the Type 1 films to be lower than the Type 2 films. The n and k values were n=1.79 and k=2.8x10-3, and n=2.08 and k=3.6x10-3 at 550 nm, for Type 1 and Type 2 films respectively. Both types of tungsten oxide films showed low absorption and high transparency in the visible range. As expected, we found that the film density, and hence the refractive index and extinction coefficient, depended on coating solution chemistry, hydration, and densification procedures. Undoped Type 1 films showed slightly higher lithium diffusion coefficients (DLi), compared to undoped Type 2 films,\ DLi=1.36x 10-9 cm2 s-1 and 1.31 x 10-9 cm2 s-1, respectively.

We also noted that the properties of the films could be reproduced for any coating chemistry and densification scheme. The electrochemical and optical behavior were determined by using an in-situ cuvette cell with a 1M LiCl04 / propylene carbonate electrolyte. Cyclic voltammetric measurements showed that doped Type 1 films exhibited electrochemical reversibility beyond 1200 cycles without change in charge capacity. A slight lowering of charge capacity was noted for the undoped films after cycling. The charge capacity for the V doped film was 16.9 mC/cm2 compared to undoped film, 9.6 mC/cm2. Spectrophotometry showed that doped films tended to exhibit a higher absorbance in their colored state compared to undoped films. Considerable improvement in the lithium diffusivity was noted for all the doped films. The greatest change was a factor of 20x for vanadium doping. Doping appeared to increase the cyclic durability of all the tungsten films out to 1200 cycles. Color changes by doping were noted for several dopants. The doped films with the best overall properties were about 8\% vanadium and titanium tungsten oxide. The optimum concentration lies in the range of 7 to 12 mol\%. The electrochromic color was a neutral brownish-blue for vanadium and grayish-blue for titanium doped tungsten oxide.

}, author = {Nilg{\"u}n {\"O}zer and Carl M Lampert and Michael D. Rubin} } @article {12146, title = {Optical Indices of Electrochromic Tungsten Oxide}, journal = {Thin Solid Films}, volume = {306}, number = {1}, year = {1996}, month = {08/1997}, pages = {10-16}, chapter = {10}, abstract = {

Tungsten trioxide (WO3) is the most widely used material for the active layer of electrochromic devices. Knowledge of the complex refractive index over the range of coloration states is required for device design. Optical constants of WO3 over the whole solar spectrum were determined as a function of injected charge. Films of WO3 were prepared by electron-beam evaporation, then colored in several steps by reduction with lithium (Li) up to 68 mC cm-2 {\textmu}m-1 injected charge. Measurements included variable-angle spectroscopic ellipsometry and spectroscopic transmittance and reflectance at normal incidence. Analysis was complicated by the fact that a transparent-conducting layer of indium tin oxide (ITO) was required to perform lithiation. Optical indices of the glass substrate and ITO transparent conductor were determined separately and then fixed in the model. The indices of WO3 could then be extracted from measurements on the complete structure. A parametric dispersion model corresponding to Gaussian broadening of the oscillators was used to represent the dielectric response of WO3.

}, keywords = {Colored state, Complex refractive index, electrochromic, tungsten oxide}, doi = {10.1016/S0040-6090(97)00254-X}, author = {Klaus von Rottkay and Michael D. Rubin and Shi-Jie Wen} } @article {12147, title = {Optical Indices of Lithiated Electrochromic Oxides}, journal = {Solar Energy Materials and Solar Cells}, volume = {54}, number = {4-Jan}, year = {1996}, month = {07/1998}, pages = {49-57}, chapter = {49}, abstract = {

Optical indices have been determined for thin films of several electrochromic oxide materials. One of the most important materials in electrochromic devices, WO3, was thoroughly characterized for a range of electrochromic states by sequential injection of Li ions. Another promising material, Li0.5Ni0.5O, was also studied in detail. Less detailed results are presented for three other common lithium-intercalating electrochromic electrode materials: V2O5, LiCoO2, and CeO2-TiO2. The films were grown by sputtering, pulsed laser deposition (PLD) and sol-gel techniques. Measurements were made using a combination of variable-angle spectroscopic ellipsometry and spectroradiometry. The optical constants were then extracted using physical and spectral models appropriate to each material. Optical indices of the underlying transparent conductors, determined in separate studies, were fixed in the models of this work. The optical models frequently agree well with independent physical measurements of film structure, particularly surface roughness by atomic force microscopy. Inhomogeneity due to surface roughness, gradient composition, and phase separation are common in both the transparent conductors and electrochromics, resulting sometimes in particularly complex models for these materials. Complete sets of data are presented over the entire solar spectrum for a range of colored states. This data is suitable for prediction of additional optical properties such as oblique transmittance and design of complete electrochromic devices.

}, doi = {10.1016/S0927-0248(97)00222-5}, author = {Michael D. Rubin and Klaus von Rottkay and Shi-Jie Wen and Nilg{\"u}n {\"O}zer and Jonathan L. Slack} } @conference {12148, title = {Optical Indices of Pyrolitic Tin-Oxide Glass}, booktitle = {Materials Research Society 1996 Spring Meeting}, volume = {426}, year = {1996}, month = {04/1996}, address = {San Francisco, CA}, abstract = {

SnO2:F is a widely used transparent conductor and commercially available in a multilayer structure as Tech glass. Current applications include photovoltaics, electrochromics and displays. Optical design of these and other applications requires knowledge of the optical constants, in some cases, over the whole solar spectrum. Various optical property measurements were performed including variable angle spectroscopic ellipsometry, and spectral transmittance and reflectance measurements. This material is deposited in several steps and has a fairly complex structure. The measured data were fit to models based on this structure to obtain the optical indices. Atomic force microscopy confirmed the optically modeled surface roughness.

}, author = {Klaus von Rottkay and Michael D. Rubin} } @conference {12150, title = {Optical Modeling of a Complete Electrochromic Device}, booktitle = {2nd International Conference on Electrochromics}, year = {1996}, month = {10/1996}, address = {San Diego, CA}, abstract = {

Optical indices have been determined for thin films of all materials needed to model a typical electrochromic device. Two electrochromic materials, tungsten oxide and lithium nickel oxide, are widely used in electrochromic devices. The optical indices of the underlying transparent conductors as well as a polymer electrolyte were also analyzed. The optical data was obtained using a combination of variable-angle spectroscopic ellipsometry and spectroradiometry. The data was then fit to appropriate models of structure and dispersion in order to extract the optical indices of the materials. First, the optical indices of the transparent conductive substrates were obtained and fixed in the model. The best models correspond well to independent physical measurements of film structure, such as atomic-force microscopy and surface profiling. Surface roughness, gradient composition and other types of inhomogeneity are common in both the transparent conductors and electrochromic, resulting in particularly complex models. The polymer has a homogeneous structure, but obtaining optically smooth surfaces was a problem. Complete sets of data were produced over the entire solar spectrum for a range of colored states of the films. Using the data for each layer, a realistic electrochromic device was simulated.

}, author = {Klaus von Rottkay and Michael D. Rubin and John B. Kerr} } @conference {12157, title = {Origin of Strain in GaN Thin Films}, booktitle = {23rd International Conference on the Physics of Semiconductors}, volume = {4}, year = {1996}, pages = {513}, address = {Singapore}, abstract = {

Photoluminescence measurements are used to determine the strain in GaN thin films grown by Molecular Beam Epitaxy. The strain which originates from growth on lattice mismatched substrates and from differences in thermal expansion coefficients is found to be greatly relaxed. Residual strains are shown to depend on the thickness of GaN buffer layers and the III/V flux ration during main layer growth. The results strongly suggest that the residual biaxial strain caused by the post-growth cooling can be modified by the incorporation of point defects during the main layer growth which introduce an additional hydrostatic strain field. The effect allows for strain engineering of GaN crystals.

}, author = {Christian F. Kisielowski and Joachim Kr{\"u}ger and Michael S.H. Leung and Ralf Klockenbrink and Hiroaki Fujii and Tadeusz Suski and Sudhir G. Subramanya and Joel W. Ager III and Michael D. Rubin and Eicke R. Weber}, editor = {Joachim Kr{\"u}ger} } @article {12140, title = {Optical and Electrochemical Characteristics of Niobium Oxide Films Prepared by Sol-Gel Process and Magnetron Sputtering: A Comparison}, journal = {Solar Energy Materials and Solar Cells}, volume = {40}, number = {4}, year = {1995}, month = {08/1996}, pages = {285-296}, chapter = {285}, abstract = {

Electrochromic niobia (Nb205) coatings were prepared by the sot-gel spin-coating and d.c. magnetron sputtering techniques. Parameters were investigated for the process fabrication of sol-gel spin coated Nb205 films exhibiting high coloration efficiency comparable with that d.c. magnetron sputtered niobia films. X-ray diffraction studies (XRD) showed that the sot-gel deposited and magnetron sputtered films heat treated at temperatures below 450{\textdegree}C, were amorphous, whereas those heat treated at higher temperatures were slightly crystalline. X-ray photoelectron spectroscopy (XPS) studies showed that the stoichiometry of the films was Nb205. The refractive index and electrochromic coloration were found to depend on the preparation technique. Both films showed low absorption and high transparency in the visible range. We found that the n, k values of the sot-gel deposited films to be lower than for the sputtered films. The n and k values were n = 1.82 and k = 3 {\texttimes} 10-3, and n = 2.28 and k = 4 {\texttimes} 10-3 at 530 urn for sot-gel deposited and sputtered films, respectively. The electrochemical behavior and structural changes were investigated in 1 M LiC104/propylene carbonate solution. Using the electrochemical measurements and X-ray photoelectron spectroscopy, the probable electrode reaction with the lithiation and delithiation is Nb2O5 + x Li+ + x e- <-> LixNb205. Cyclic voltametric (CV) measurements showed that both Nb205 films exhibits electrochemical reversibility beyond 1200 cycles without change in performance. {\textquotedblleft}In situ{\textquotedblright} optical measurement revealed that those films exhibit an electrochromic effect in the spectral range 300 \< λ \< 2100 nm but remain unchanged in the infrared spectral range. The change in visible transmittance was 40\% for 250 nm thick electrodes. Spectroelectrochemical measurements showed that spin coated films were essentially electrochemically equivalent to those prepared by d.c. magnetron sputter deposition.

}, keywords = {D.C. magnetron sputtering, electrochromism, Niobia, optical properties, sol-gel deposition}, doi = {10.1016/0927-0248(95)00147-6}, author = {Nilg{\"u}n {\"O}zer and Carl M Lampert and Michael D. Rubin} } @conference {12141, title = {Optical and Electrochemical Properties of Sol-gel Spin Coated CeO2-TiO2 Films}, booktitle = {SPIE Meeting}, year = {1995}, month = {07/1995}, address = {San Diego, CA}, abstract = {

The optical and electrochemical properties of sol-gel spin coated Ce02-TiO2 (50\% CeO2) films were investigated for electrochrornic applications. The coating solutions were prepared by using mixed organic-inorganic | Ti(OC2H5)4 and Ce(NH4)2 (NO3)6 | precursors. X-ray diffraction studies showed the sol-gel spin-coated films were composed of an amorphous matrix of titanium oxide containing nanocrystallites of cerium oxide. The coating solar transmission value was Ts=0.8 (250 nm thick). The refractive index and the extinction coefficient were derived from transmittance measurements in the UV-VIS-NIR regions. These films had refractive index value of n=2.18 and extinction coefficient value of k=8x10-4 at λ=550 nm. Cyclic voltametric measurements showed reversible electrochemical insertion of lithium ions in a CeO2-TiO2/LiClO4-propylene carbonate electrochemical cell. During cycling the films maintain high optical transmittance. Spectrophotometric and electrochemical investigations performed on CeO2-TiO2 films revealed that these films are suitable as an optically passive counter-electrode in lithium electrochromic devices.

}, keywords = {cerium oxide-titanium oxide, counter electrode, electrochemical properties, electrochromic device, optical properties, sol-gel deposition}, author = {Nilg{\"u}n {\"O}zer and Selmar DeSouza and Carl M Lampert} } @conference {12149, title = {Optical Indices of the Tin-doped Indium Oxide and Tungsten Oxide Electrochromic Coatings}, booktitle = {Material Research Society Symposium }, volume = {403}, year = {1995}, pages = {551-556}, abstract = {

Thin films of tin-doped indium oxide are widely used for transparent conductors. One application of In2O3:Sn (ITO) is transparent contacts for electrochromic electrodes. Optical design of electrochromic devices requires knowledge of the optical constants for each layer from the near ultraviolet and visible to the mid infrared. Determination of the optical constants of the electrochromic layer cannot be made in isolation; a complete device or at least a half-cell including a layer of ITO is required to change the optical state of the electrochromic material. Measurements on ITO were made using variable-angle spectral ellipsometry, and spectral transmittance and reflectance. A series of structural models were fit to this data. The problem is complicated because of inhomogeneity in the films, variability in the manufacturing process, and sensitivity to environmental conditions. The spectral dependency was modeled by a single Lorentz oscillator and a Drude free-electron component. This data was then used as the basis for a model to extract the optical constants for a tungsten oxide electrochromic film.

}, author = {Klaus von Rottkay and Michael D. Rubin and Nilg{\"u}n {\"O}zer} } @conference {12128, title = {Office Lighting: A Review of 80 Years of Standards and Recommendations}, booktitle = {1993 IEEE Industry Applications Society Annual Meeting}, year = {1993}, month = {10/1993}, address = {Toronto, Canada}, abstract = {

This paper traces the development of quantitative office lighting standards from its beginnings to the present. It discusses the sources of recommended lighting practice, the nature of the quantitative recommendations, and trends in recommended values on a comparative basis. A critical assessment of contemporary standards is provided within this historical context.

}, author = {Werner K.E. Osterhaus} } @article {12154, title = {Optical Switching Technology for Glazing}, journal = {Thin Solid Films}, volume = {236}, number = {2-Jan}, year = {1993}, month = {12/1993}, pages = {6-13}, chapter = {6}, abstract = {

The technology of optical switching devices for dynamic glazings and other applications is discussed. The status of the state of the industry and its developments is detailed. The technical emphasis will be on the properties of chromogenic materials covering electrochromic, phase-dispersed liquid crystals and dispersed-particle systems. Such technologies can be used for dynamic control of solar energy through building and vehicle glazings. Both visible and solar control can be obtained from these devices. Switching ranges can be from as high as 80\% to 5-10\% transmittance in the visible region. The energy and daylighting benefits of such glazings are discussed. Also, chromogenic glazings can be used for other product applications such as the modulation of reflector surfaces and large electronic information display systems. The science of selected electrochromic devices is covered. Technical issues concerning large-scale chromogenic devices are discussed.

}, doi = {10.1016/0040-6090(93)90633-Z}, author = {Carl M Lampert} } @conference {12156, title = {Optimizing the Effective Conductivity and Cost of Gas-Filled Panel Thermal Insulations}, booktitle = {22nd International Thermal Conductivity Conference}, year = {1993}, month = {11/1993}, address = {Tempe, AZ}, abstract = {

Gas-Filled Panels, or GFPs, are an advanced theimal insulation that employ a low-conductivity, inert gas, at atmospheiic pressure, within a multilayer reflective baffle. The thermal performance of GFPs varies with gas conductivity, overall panel thickness, and baffle construction. Design parameters of baffle constructions that have a strong effect on GFP thermal resistance are (1) cavities per thickness, (2) cavity surface emittance, and (3) conductance of the baffle materials. GFP thermal performances, where the above parameters were varied, were modeled on a spreadsheet by iterative calculation of one-dimensional energy balances. Heat flow meter apparatus measurements of prototype GFP effective conductivities have been made and are compared to results of the calculations. The costs associated with varying baffle constructions are estimated based on the prices of commercial material components. Results are presented in terms of cost per area per unit thermal resistance ($/Area*R-Value) and are usefid for optimizing GFP designs forsair, argon, or krypton gas fills and a desired effective conductivity and thickness.

}, author = {Brent T. Griffith and Daniel Turler and Dariush K. Arasteh} }