@article {12195, title = {Preparation and Properties of Spin-Coated Nb2O5 Films by the Sol-Gel Process for Electrochemical Applications}, journal = {Thin Solid Films}, volume = {277}, number = {2-Jan}, year = {1995}, month = {05/1996}, pages = {162-168}, chapter = {162}, abstract = {

The preparation and properties of Nb2O5 coatings made by the sol-gel process were investigated. The films were deposited by spin coating on In2O3:Sn/glass and quartz substrates from a polymeric solutions of niobia derived from niobium ethoxide. The films were characterized by investigation of the stoichiometry, refractive index, optical transmission, electrochemical behavior, and the microstructure. X-ray diffraction studies showed the films to be amorphous for heat treatments below 450 {\textdegree}C. X-ray photoelectron spectroscopy (XPS) measurement revealed the O:Nb atomic stoichiometry to be 5:2. Cyclic voltammetric measurements showed that the Nb2O5/1 M LiClO4-propylene carbonate system exhibits electrochemical reversibility beyond 1200 cycles without change in performance. In situ UV-Vis-NIR spectroelectrochemical measurement revealed that Nb2O5 films exhibit an electrochromic effect in the spectral range 300\<λ\<2100 nm and remain unchanged in the infrared spectral range. The change in visible transmittance was 40\% for a 250 nm thick electrode. XPS spectra indicate that Nb(V) is reduced to a lower valence state Nb(IV) in a colored state with injected Li+. The bronze coloration is due to a simultaneous injection of electrons and Li+ ions into Nb2O5. The sol-gel-deposited\ Nb2O5 films are useful for cathodically coloring electrochromic electrodes in electrochromic devices.

}, keywords = {Electrochemistry, Niobium oxide, optical properties, X-ray photoelectron spectroscopy}, url = {http://dx.doi.org/10.1016/0040-6090(95)08011-2}, author = {Nilg{\"u}n {\"O}zer and Din-Guo Chen and Carl M Lampert} }