@conference {1854, title = {Structural and Electronic Properties of Magnesium-3D Transition Metal Switchable Mirrors}, booktitle = {Fifth International Meeting on Electrochromism}, year = {2002}, month = {12/2002}, address = {Golden, CO}, abstract = {

We have observed reversible mirror-to-transparent state switching in a variety of mixed metal thin films containing magnesium and first-row transition elements including Ni, Fe, Co, Mn, and Ti. The very large changes in both reflectance and transmittance on loading these films with hydrogen are accompanied by significant structural and electronic transformations. The valence states and coordination of metal atoms during hydrogen loading were followed using dynamic in situ transmissionmode X-ray absorption spectroscopy. Time-resolved Mg K-edge and Ni, Co, Mn, and Ti L-edge spectra reflect both reversible and irreversible changes in the metal environments. These spectra are compared to those of reference materials and to predictions from calculations.

}, keywords = {EXAFS, Hydrogen storage materials, NEXAFS, thin films, x-ray diffraction}, doi = {10.1016/j.ssi.2003.08.041}, author = {Baker Farangis and Ponnusamy Nachimuthu and Thomas J. Richardson and Jonathan L. Slack and Bruno K. Meyer and Rupert C.C. Perera and Michael D. Rubin} } @article {1875, title = {Switchable Mirrors Based on Nickel-Magnesium Films}, journal = {Applied Physics Letters}, volume = {78}, number = {20}, year = {2001}, month = {05/2001}, pages = {3047-3049}, chapter = {3047}, abstract = {

An electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin, magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on cathodic polarization in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction, and to protect the metal surface against oxidation.

}, doi = {10.1063/1.1371959 }, author = {Thomas J. Richardson and Jonathan L. Slack and Robert D. Armitage and Robert Kostecki and Baker Farangis and Michael D. Rubin} } @article {1828, title = {Solid State Gadolinium-Magnesium Hydride Optical Switch}, journal = {Applied Physics Letters}, volume = {75}, number = {13}, year = {1999}, month = {09/1999}, pages = {1863-1865}, chapter = {1863}, abstract = {

The optical switching properties of gadolinium-magnesium hydride have been demonstrated in a solid-state electrochromic device. With positive polarization of the hydride electrode, the visible reflectance approaches 35\% with virtually zero transmission, while with negative polarization, the visible transmission exceeds 25\% at 650 nm. The switching is reversible, with intermediate optical properties between the transparent and reflecting states.

}, url = {http://dx.doi.org/10.1063/1.124853}, author = {Robert D. Armitage and Michael D. Rubin and Thomas J. Richardson and Nada O{\textquoteright}Brien and Yong Chen} } @conference {1847, title = {State-of-the-Art Software for Window Energy-Efficiency Rating and Labeling}, booktitle = {ACEEE 1998 Summer Study on Energy Efficiency in Buildings}, year = {1998}, month = {08/1998}, address = {Pacific Grove, CA}, abstract = {

Measuring the thermal performance of windows in typical residential buildings is an expensive proposition. Not only is laboratory testing expensive, but each window manufacturer typically offers hundreds of individual products, each of which has different thermal performance properties. With over a thousand window manufacturers nationally, a testing-based rating system would be prohibitively expensive to the industry and to consumers.

Beginning in the early 1990s, simulation software began to be used as part of a national program for rating window U-values. The rating program has since been expanded to include Solar Hear Gain Coefficients and is now being extended to annual energy performance.

This paper describes four software packages available to the public from Lawrence Berkeley National Laboratory (LBNL). These software packages are used to evaluate window thermal performance: RESFEN (for evaluating annual energy costs), WINDOW (for calculating a products thermal performance properties), THERM (a preprocessor for WINDOW that determines two-dimensional heat-transfer effects), and Optics (a preprocessor for WINDOWs glass database).

Software not only offers a less expensive means than testing to evaluate window performance, it can also be used during the design process to help manufacturers produce windows that will meet target specifications. In addition, software can show small improvements in window performance that might not be detected in actual testing because of large uncertainties in test procedures.

}, author = {Dariush K. Arasteh and Elizabeth U. Finlayson and Yu Joe Huang and Charlie Huizenga and Robin Mitchell and Michael D. Rubin} } @conference {1817, title = {Sol-Gel Deposited Electrochromic Films for Electrochromic Smart Window Glass}, booktitle = {International Symposium on Glass Problems, International Commission on Glass}, year = {1996}, month = {09/1996}, address = {Istanbul, Turkey}, abstract = {

Electrochrornic windows offer the ability to dynamically change the transmittance of a glazing. With the appropriate sensor and controls, this smart window can be used for energy regulation and glare control for a variety of glazing applications. The most promising are building and automotive applications. This work covers the use of sol-gel deposition processes to make active films for these windows. The sol-gel process offers a low-capital investment for the deposition of these active films. Sol-gel serves as an alternative to more expensive vacuum deposition processes. The sol-gel process utilizes solution coating followed by a hydrolysis and condensation. In this investigation we report on tungsten oxide and nickel oxide films made by the sol-gel process for electrochromic windows. The properties of the sol-gel films compare favorably to those of films made by other techniques. A typical laminated electrochromic window consists of two glass sheets coated with transparent conductors, which are coated with the active films. The two sheets are laminated together with an ionically conductive polymer. The range of visible transmission modulation of the tungsten oxide was 60\% and for the nickel oxide was 20\%. We used the device configuration of glass/SnO2:F/WO3/polymer/LizNiOxHy/SnO2:F to test the films. The nickel oxide layer had a low level of lithiation and possibly contained a small amount of water. Lithiated oxymethylene-linked poly(ethylene oxide) was used as the laminating polymer. Commercially available Sn02:F/glass (LOF-Tec glass) was used as the transparent conducting glass. We found reasonable device switching characteristics which could be used for devices.

}, author = {Nilg{\"u}n {\"O}zer and Carl M Lampert and Michael D. Rubin} } @article {1849, title = {Strain Related Phenomena in GaN Thin Films}, journal = {Physical Review B}, volume = {54}, number = {24}, year = {1996}, month = {12/1996}, pages = {17745-17753}, chapter = {17745}, abstract = {

Photoluminescence (PL), Raman spectroscopy, and x-ray diffraction are employed to demonstrate the co-existence of a biaxial and a hydrostatic strain that can be present in GaN thin films. The biaxial strain originates from growth on lattice-mismatched substrates and from post-growth cooling. An additional hydrostatic strain is shown to be introduced by the presence of point defects. A consistent description of the experimental results is derived within the limits of the linear and isotropic elastic theory using a Poisson ratio nu =0.23+/-0.06 and a bulk modulus B=200+/-20 GPa. These isotropic elastic constants help to judge the validity of published anisotropic elastic constants that vary greatly. Calibration constants for strain-induced shifts of the near-band-edge PL lines with respect to the E2 Raman mode are given for strain-free, biaxially strained, and hydrostatically contracted or expanded thin films. They allow us to extract differences between hydrostatic and biaxial stress components if present. In particular, we determine that a biaxial stress of one GPa would shift the near-band-edge PL lines by 27+/-2 meV and the E2 Raman mode by 4.2+/-0.3 cm-1 by use of the listed isotropic elastic constants. It is expected from the analyses that stoichiometric variations in the GaN thin films together with the design of specific buffer layers can be utilized to strain engineer the material to an extent that greatly exceeds the possibilities known from other semiconductor systems because of the largely different covalent radii of the Ga and the N atom.

}, doi = {10.1103/PhysRevB.54.17745}, author = {Christian F. Kisielowski and Joachim Kr{\"u}ger and Sergei Ruvimov and Tadeusz Suski and Joel W. Ager III and Erin C. Jones and Zuzanna Liliental-Weber and Michael D. Rubin and Eicke R. Weber and Michael D. Bremser and Robert F. Davis}, editor = {Joachim Kr{\"u}ger} } @conference {1801, title = {Simulating the Energy Performance of Holographic Glazings}, booktitle = {13th SPIE International Symposium on Optical Materials Technology for Energy Efficiency and Solar Energy Conversion}, year = {1994}, month = {04/1994}, address = {Freiburg, Germany}, abstract = {

The light diffraction properties of holographic diffractive structures present an opportunity to improve the daylight performance in side-lit office spaces by redirecting and reflecting sunlight off the ceiling, providing adequate daylight illumination up to 30 ft (9.14 m) from the window wall. Prior studies of prototypical holographic glazings, installed above conventional view windows, have shown increased daylight levels over a deeper perimeter area than clear glass, for selected sun positions. In this study, we report on the simulation of the energy performance of prototypical holographic glazings assuming a commercial office building in the inland Los Angeles climate.

The simulation of the energy performance involved determination of both luminous and thermal performance. Since the optical complexity of holographic glazings prevented the use of conventional algorithms for the simulation of their luminous performance, we used a newly developed method that combines experimentally determined directional workplane illuminance coefficients with computer-based analytical routines to determine a comprehensive set of daylight factors for many sun positions. These daylight factors were then used within the DOE-2.1D energy simulation program to determine hourly daylight and energy performance over the course of an entire year for four window orientations.

Since the prototypical holographic diffractive structures considered in this study were applied on single pane clear glass, we also simulated the performance of hypothetical glazings, assuming the daylight performance of the prototype holographic glazings and the thermal performance of double-pane and low-e glazings. The results of our analyses show that these prototypical holographic glazings did not save significant electric energy or reduce peak electricity demand compared to conventional energy-efficient window systems in inland Los Angeles office buildings, mainly because of their low diffraction efficiency. Finally, we address various design and implementation issues towards potential performance improvement.

}, author = {Konstantinos M. Papamichael and Liliana O. Beltran and Reto A. Furler and Eleanor S. Lee and Stephen E. Selkowitz and Michael D. Rubin} } @article {1837, title = {Spectrally Selective Glazings for Residential Retrofits in Cooling-Dominated Climates}, journal = {ASHRAE Transactions}, volume = {100}, year = {1994}, abstract = {

Spectrally selective glazings can substantially reduce energy consumption and peak demand in residences by significantly reducing solar gains with minimal loss of illumination and view. In cooling-dominated climates, solar gains contribute 24{\textendash}31\% to electricity consumption and 40{\textendash}43\% to peak demand in homes with single pane clear glazing{\textemdash}standard practice for residential construction built before the implementation of building energy efficiency standards. The existing residential housing stock therefore offers a prime opportunity for significant demand-side management (DSM),but the energy and cost savings must be weighed against retrofit first costs in order for the technology to achieve full market penetration. Using DOE-2.1D for numerical simulation of building energy performance, we quantify the energy and peak demand reductions, cost savings, and HVAC capacity reductions using spectrally selective glazings for five cooling-dominated climates in California. The cost-effectiveness of various material and installation retrofit options is discussed. Glazing material improvements for retrofit applications that are needed to achieve a prescribed cost savings are also given.

}, keywords = {deserts, domestic, energy conservation, Glazing, housing, modernising, subtropics, usa, windows}, author = {Eleanor S. Lee and Deborah Hopkins and Michael D. Rubin and Dariush K. Arasteh and Stephen E. Selkowitz} }