01659nas a2200193   4500008004100000050001500041245009400056210006900150260002500219520098200244100002301226700002301249700002101272700002501293700002701318700002401345700002101369856007501390       1998                        eng d  aLBNL-4227700aEffect of Hydrogen Insertion on the Optical Properties of PD-Coated Magnesium Lanthanides0 aEffect of Hydrogen Insertion on the Optical Properties of PDCoat  aLondon, U.K.c9/19983 a<p>Metallic magnesium lanthanide thin films upon insertion of hydrogen transform to a highly transparent hydride phase. With a Pd overlayer, the transformation can be produced either by electrochemical insertion of hydrogen or by exposing the film to hydrogen gas. Unlike amorphous oxide electrochromics, the transformation is accompanied by a large change in visible reflectance (about 50%). The optical switching effect in these materials is investigated in terms of changes in the complex refractive index as determined by variable-angle spectroscopic ellipsometric and normal-incidence radiometric measurements over the solar spectrum. Furthermore the optical effect of converting the Pd caplayer to Pd-H was determined. It is shown that the pd layer limits the visible transmittance of the hyrdrided stack to about 35-40%. Whereas the extinction coefficient of the dehydrided LnMg-layers at 550 nm is between 2.2 and 3.1, it is as low as 10-4 in the transparent state.</p>1 avon Rottkay, Klaus1 aRubin, Michael, D.1 aMichalak, Franck1 aArmitage, Robert, D.1 aRichardson, Thomas, J.1 aSlack, Jonathan, L.1 aDuine, Peter, A.  uhttps://facades.lbl.gov/publications/effect-hydrogen-insertion-optical