01580nas a2200253 4500008003900000022001300039245007700052210006900129260001100198300001400209490000700223520083600230653000901066653000901075653001801084653002301102653002101125100002301146700002301169700002401192700002101216700001501237856007401252 2009 d a0925346700aOptical characterization of fritted glass for architectural applications0 aOptical characterization of fritted glass for architectural appl c4/2009 a949 - 9580 v313 a

Fritted glass is commonly used as a light diffusing element in modern buildings. Traditionally it has been used for aesthetic purposes but it can also be used for energy savings by incorporating it in novel daylighting systems? To answer such questions the light scattering properties must be properly characterized.

This paper contains measurements of different varieties of fritted glass, ranging from the simplest direct-hemispherical measurements to angle-resolved goniometer measurements. Modeling the light scattering to obtain the full bidirectional scattering distribution function (BSDF) extends the measured data, making it useful in simulation programs such as Window 6 and Radiance. Surface profilometry results and SEM micrographs are included to demonstrate the surface properties of the samples studied.

10aBRDF10aBTDF10aFritted glass10aIntegrating sphere10alight scattering1 aJonsson, Jacob, C.1 aRubin, Michael, D.1 aNilsson, Annica, M.1 aJonsson, Andreas1 aRoos, Arne uhttps://facades.lbl.gov/publications/optical-characterization-fritted01008nas a2200157 4500008004100000245008100041210006900122260001200191300001000203490000700213520048800220100002200708700002800730700001900758856007300777 2008 eng d00aObservation of Ti4+ ions in a high power impulse magnetron sputtering plasma0 aObservation of Ti4 ions in a high power impulse magnetron sputte c08/2008 a715040 v933 a

Multiply charged titanium ions including Ti4+ were observed in high power impulse magnetron sputtering discharges. Mass/charge spectrometry was used to identify metal ion species. Quadruply charged titanium ions were identified by isotope-induced broadening at mass/charge 12. Due to their high potential energy, Ti4+ ions give a high yield of secondary electrons, which in turn are likely to be responsible for the generation of multiply charged states.

1 aAndersson, Joakim1 aEhiasarian, Arutiun, P.1 aAnders, André uhttps://facades.lbl.gov/publications/observation-ti4-ions-high-power01753nas a2200145 4500008004100000050001500041245012900056210006900185300001200254490000800266520121600274100002301490700002001513856007401533 2007 eng d aLBNL-6182600aObtaining the Bidirectional Transfer Distribution Function of Isotropically Scattering Materials Using an Integrating Sphere0 aObtaining the Bidirectional Transfer Distribution Function of Is a228-2360 v2773 a

This paper demonstrates a method to determine the bidirectional transfer distribution function (BTDF) using an integrating sphere. Information about the sample's angle dependent scattering is obtained by making transmittance measurements with the sample at different distances from the integrating sphere. Knowledge about the illuminated area of the sample and the geometry of the sphere port in combination with the measured data combines to an system of equations that includes the angle dependent transmittance. The resulting system of equations is an ill-posed problem which rarely gives a physical solution. A solvable system is obtained by using Tikhonov regularization on the ill-posed problem. The solution to this system can then be used to obtain the BTDF. Four bulk-scattering samples were characterised using both two goniophotometers and the described method to verify the validity of the new method. The agreement shown is great for the more diffuse samples. The solution to the low-scattering samples contains unphysical oscillations, but still gives the correct shape of the solution. The origin of the oscillations and why they are more prominent in low-scattering samples are discussed.

1 aJonsson, Jacob, C.1 aBranden, Henrik uhttps://facades.lbl.gov/publications/obtaining-bidirectional-transfer01152nas a2200133 4500008004100000050001500041245007500056210006900131300001400200490000700214520069900221100001900920856007900939 2004 eng d aLBNL-5587600aObservation of Self-Sputtering in Energetic Condensation of Metal Ions0 aObservation of SelfSputtering in Energetic Condensation of Metal a6137-61390 v853 a

The condensation of energetic metal ions on a surface may cause self-sputtering even in the absence of substrate bias. Charge-state-averaged self-sputtering yields were determined for both zirconium and gold ions generated by a cathodic vacuum arc. Films were deposited on differently biased substrates exposed to streaming Zr and Au vacuum arc plasma. The self-sputtering yields for both metals were estimated to be about 0.05 in the absence of bias, and exceeding 0.5 when bias reached - 50 V. These surprisingly high values can be reconciled with binary collision theory and molecular dynamics calculations taking high the kinetic and potential energy of vacuum arc ions into account.

1 aAnders, André uhttps://facades.lbl.gov/publications/observation-self-sputtering-energetic00433nas a2200133 4500008004100000050001500041245002600056210002400082260006700106100002200173700002000195700002300215856006100238 2002 eng d aLBNL-5214800aOptics Version 5.1.010 aOptics Version 5101 aBerkeley, CAbRegents of the University of Californiac11/20021 aVersluis, Richard1 aPowles, Rebecca1 aRubin, Michael, D. uhttps://facades.lbl.gov/publications/optics-version-510101358nas a2200145 4500008004100000050001500041245006400056210006400120260002700184300001000211520087000221100002301091700002001114856007801134 2000 eng d aLBNL-4832200aOptical Properties of Glazing Materials at Normal Incidence0 aOptical Properties of Glazing Materials at Normal Incidence aParis, Francec10/2000 a13-163 a

Measurements of spectral transmittance T and reflectance R at normal incidence continue to be the most common and accurate source of energy performance data for glazing materials. Prediction of these radiometric properties from more fundamental materials data is often confounded by the complexity and uncertainty of coating structures. Angle-dependent radiometric properties of coated glazing will probably be predicted from normal-incidence data rather than being measured at many angles. The general error level demonstrated in round-robin tests is on the order 1-2%; it is often necessary to achieve better levels of performance. Based on results obtained following the round-robin tests, it is expected that accuracy of better than 0.5% can be generally achieved. A new type of absolute standard reference is described and tested with promising results.

1 aRubin, Michael, D.1 aPowles, Rebecca uhttps://facades.lbl.gov/publications/optical-properties-glazing-materials01544nas a2200241 4500008004100000245010200041210006900143260001200212300001200224490000700236520078600243653001301029653001201042653002501054653001601079653001301095100002101108700002101129700002201150700002901172700002701201856007401228 1998 eng d00aOffice Worker Response to an Automated Venetian Blind and Electric Lighting System: A Pilot Study0 aOffice Worker Response to an Automated Venetian Blind and Electr c10/1998 a205-2180 v283 a

A prototype integrated, dynamic building envelope and lighting system designed to optimize daylight admission and solar heat gain rejection on a real-time basis in a commercial office building is evaluated. Office worker response to the system and occupant-based modifications to the control system are investigated to determine if the design and operation of the prototype system can be improved. Key findings from the study are: (1) the prototype integrated envelope and lighting system is ready for field testing, (2) most office workers (N=14) were satisfied with the system, and (3) there were few complaints. Additional studies are needed to explain how illuminance distribution, lighting quality, and room design can affect workplane illuminance preferences.

10abehavior10aComfort10acommercial buildings10adaylighting10aenvelope1 aVine, Edward, L.1 aLee, Eleanor, S.1 aClear, Robert, D.1 aDiBartolomeo, Dennis, L.1 aSelkowitz, Stephen, E. uhttps://facades.lbl.gov/publications/office-worker-response-automated01350nas a2200181 4500008004100000245007700041210006900118260001200187300001400199490000700213520076000220100002100980700001901001700002501020700002301045700002301068856007701091 1998 eng d00aOptical Constants of Sputter-Deposited Ti-Ce Oxide and Zr-Ce Oxide Films0 aOptical Constants of SputterDeposited TiCe Oxide and ZrCe Oxide  c09/1998 a5993-60010 v373 a

Films of Ti oxide, Zr oxide, Ce oxide, Ti-Ce oxide, and Zr-Ce oxide were made by means of reactive dc magnetron sputtering in a multitarget arrangement. The films were characterized by x-ray diffraction and electrochemical measurements, both techniques being firmly connected to stoichiometric information. The optical constants n and k were evalued from spectrophotometry and from variable-angle spectroscopic ellipsometry. The two analyses gave consistent results. It was found that n for the mixed-oxide films varied smoothly between the values for the pure oxides, whereas k in the band-gap range showed characteristic differences between Ti-Ce oxide and Zr-Ce oxide. It is speculated that this difference is associated with structural effects.

1 aVeszelei, Monica1 aKullman, Lisen1 aGranqvist, Claes, G.1 avon Rottkay, Klaus1 aRubin, Michael, D. uhttps://facades.lbl.gov/publications/optical-constants-sputter-deposited03663nas a2200133 4500008003900000245009000039210006900129260002200198520316700220100001903387700002103406700002303427856007903450 1996 d00aOptical and Electrochromic Properties of Sol-Gel Deposited Doped Tungsten Oxide Films0 aOptical and Electrochromic Properties of SolGel Deposited Doped  aBerkeleyc01/19963 a

The goal of this study is to investigate the effects of doping of tungsten oxide on its electrochromic properties. The work is directed toward the development of neutral coloring tungsten oxide materials with properties superior to undoped tungsten oxide. Two basic types of sol-gel formulations were used for experimentation. Type 1 used a WOCl4 precursor. Type 2 used a proprietary (Donnelly) tungsten complex precursor. The Type 2 precursor was used only for comparison to Type 1. Doping experiments were performed using the Type 1 chemistry. The dopants studied were Co, Cr, Nb, Ti, V and Y. The range of dopant was 1-12 mole %. Improved electrochromic behavior was observed for tungsten oxide films doped with V and Ti.

Analysis of the films included x-ray diffraction, ellipsometry, cyclic voltammetry and spectrophotometry. X-ray diffraction showed that all films heat treated at temperatures below 300°C were amorphous in structure. The refractive indices for undoped films were measured. We found the n, k values of the Type 1 films to be lower than the Type 2 films. The n and k values were n=1.79 and k=2.8x10-3, and n=2.08 and k=3.6x10-3 at 550 nm, for Type 1 and Type 2 films respectively. Both types of tungsten oxide films showed low absorption and high transparency in the visible range. As expected, we found that the film density, and hence the refractive index and extinction coefficient, depended on coating solution chemistry, hydration, and densification procedures. Undoped Type 1 films showed slightly higher lithium diffusion coefficients (DLi), compared to undoped Type 2 films, DLi=1.36x 10-9 cm2 s-1 and 1.31 x 10-9 cm2 s-1, respectively.

We also noted that the properties of the films could be reproduced for any coating chemistry and densification scheme. The electrochemical and optical behavior were determined by using an in-situ cuvette cell with a 1M LiCl04 / propylene carbonate electrolyte. Cyclic voltammetric measurements showed that doped Type 1 films exhibited electrochemical reversibility beyond 1200 cycles without change in charge capacity. A slight lowering of charge capacity was noted for the undoped films after cycling. The charge capacity for the V doped film was 16.9 mC/cm2 compared to undoped film, 9.6 mC/cm2. Spectrophotometry showed that doped films tended to exhibit a higher absorbance in their colored state compared to undoped films. Considerable improvement in the lithium diffusivity was noted for all the doped films. The greatest change was a factor of 20x for vanadium doping. Doping appeared to increase the cyclic durability of all the tungsten films out to 1200 cycles. Color changes by doping were noted for several dopants. The doped films with the best overall properties were about 8% vanadium and titanium tungsten oxide. The optimum concentration lies in the range of 7 to 12 mol%. The electrochromic color was a neutral brownish-blue for vanadium and grayish-blue for titanium doped tungsten oxide.

1 aÖzer, Nilgün1 aLampert, Carl, M1 aRubin, Michael, D. uhttps://facades.lbl.gov/publications/optical-and-electrochromic-properties01789nas a2200205 4500008004100000245005300041210005300094260001200147300001000159490000800169520118600177653001801363653002901381653001901410653001901429100002301448700002301471700001701494856007201511 1996 eng d00aOptical Indices of Electrochromic Tungsten Oxide0 aOptical Indices of Electrochromic Tungsten Oxide c08/1997 a10-160 v3063 a

Tungsten trioxide (WO3) is the most widely used material for the active layer of electrochromic devices. Knowledge of the complex refractive index over the range of coloration states is required for device design. Optical constants of WO3 over the whole solar spectrum were determined as a function of injected charge. Films of WO3 were prepared by electron-beam evaporation, then colored in several steps by reduction with lithium (Li) up to 68 mC cm-2 µm-1 injected charge. Measurements included variable-angle spectroscopic ellipsometry and spectroscopic transmittance and reflectance at normal incidence. Analysis was complicated by the fact that a transparent-conducting layer of indium tin oxide (ITO) was required to perform lithiation. Optical indices of the glass substrate and ITO transparent conductor were determined separately and then fixed in the model. The indices of WO3 could then be extracted from measurements on the complete structure. A parametric dispersion model corresponding to Gaussian broadening of the oscillators was used to represent the dielectric response of WO3.

10aColored state10aComplex refractive index10aelectrochromic10atungsten oxide1 avon Rottkay, Klaus1 aRubin, Michael, D.1 aWen, Shi-Jie uhttps://facades.lbl.gov/publications/optical-indices-electrochromic02176nas a2200181 4500008004100000245005500041210005500096260001200151300001000163490000700173520164100180100002301821700002301844700001701867700001901884700002401903856006701927 1996 eng d00aOptical Indices of Lithiated Electrochromic Oxides0 aOptical Indices of Lithiated Electrochromic Oxides c07/1998 a49-570 v543 a

Optical indices have been determined for thin films of several electrochromic oxide materials. One of the most important materials in electrochromic devices, WO3, was thoroughly characterized for a range of electrochromic states by sequential injection of Li ions. Another promising material, Li0.5Ni0.5O, was also studied in detail. Less detailed results are presented for three other common lithium-intercalating electrochromic electrode materials: V2O5, LiCoO2, and CeO2-TiO2. The films were grown by sputtering, pulsed laser deposition (PLD) and sol-gel techniques. Measurements were made using a combination of variable-angle spectroscopic ellipsometry and spectroradiometry. The optical constants were then extracted using physical and spectral models appropriate to each material. Optical indices of the underlying transparent conductors, determined in separate studies, were fixed in the models of this work. The optical models frequently agree well with independent physical measurements of film structure, particularly surface roughness by atomic force microscopy. Inhomogeneity due to surface roughness, gradient composition, and phase separation are common in both the transparent conductors and electrochromics, resulting sometimes in particularly complex models for these materials. Complete sets of data are presented over the entire solar spectrum for a range of colored states. This data is suitable for prediction of additional optical properties such as oblique transmittance and design of complete electrochromic devices.

1 aRubin, Michael, D.1 avon Rottkay, Klaus1 aWen, Shi-Jie1 aÖzer, Nilgün1 aSlack, Jonathan, L. uhttps://facades.lbl.gov/publications/optical-indices-lithiated01218nas a2200145 4500008004100000050001400041245004900055210004800104260003100152490000800183520075800191100002300949700002300972856007700995 1996 eng d aLBL-3858600aOptical Indices of Pyrolitic Tin-Oxide Glass0 aOptical Indices of Pyrolitic TinOxide Glass aSan Francisco, CAc04/19960 v4263 a

SnO2:F is a widely used transparent conductor and commercially available in a multilayer structure as Tech glass. Current applications include photovoltaics, electrochromics and displays. Optical design of these and other applications requires knowledge of the optical constants, in some cases, over the whole solar spectrum. Various optical property measurements were performed including variable angle spectroscopic ellipsometry, and spectral transmittance and reflectance measurements. This material is deposited in several steps and has a fairly complex structure. The measured data were fit to models based on this structure to obtain the optical indices. Atomic force microscopy confirmed the optically modeled surface roughness.

1 avon Rottkay, Klaus1 aRubin, Michael, D. uhttps://facades.lbl.gov/publications/optical-indices-pyrolitic-tin-oxide01797nas a2200145 4500008004100000050001500041245005700056210005700113260002700170520132200197100002301519700002301542700001901565856006701584 1996 eng d aLBNL-3959400aOptical Modeling of a Complete Electrochromic Device0 aOptical Modeling of a Complete Electrochromic Device aSan Diego, CAc10/19963 a

Optical indices have been determined for thin films of all materials needed to model a typical electrochromic device. Two electrochromic materials, tungsten oxide and lithium nickel oxide, are widely used in electrochromic devices. The optical indices of the underlying transparent conductors as well as a polymer electrolyte were also analyzed. The optical data was obtained using a combination of variable-angle spectroscopic ellipsometry and spectroradiometry. The data was then fit to appropriate models of structure and dispersion in order to extract the optical indices of the materials. First, the optical indices of the transparent conductive substrates were obtained and fixed in the model. The best models correspond well to independent physical measurements of film structure, such as atomic-force microscopy and surface profiling. Surface roughness, gradient composition and other types of inhomogeneity are common in both the transparent conductors and electrochromic, resulting in particularly complex models. The polymer has a homogeneous structure, but obtaining optically smooth surfaces was a problem. Complete sets of data were produced over the entire solar spectrum for a range of colored states of the films. Using the data for each layer, a realistic electrochromic device was simulated.

1 avon Rottkay, Klaus1 aRubin, Michael, D.1 aKerr, John, B. uhttps://facades.lbl.gov/publications/optical-modeling-complete01453nas a2200265 4500008004100000050001500041245003900056210003900095260001400134300000800148490000600156520070600162100003100868700002100899700002500920700002300945700001900968700001900987700002701006700001901033700002301052700002101075700002101096856007001117 1996 eng d aLBNL-3985300aOrigin of Strain in GaN Thin Films0 aOrigin of Strain in GaN Thin Films aSingapore a5130 v43 a

Photoluminescence measurements are used to determine the strain in GaN thin films grown by Molecular Beam Epitaxy. The strain which originates from growth on lattice mismatched substrates and from differences in thermal expansion coefficients is found to be greatly relaxed. Residual strains are shown to depend on the thickness of GaN buffer layers and the III/V flux ration during main layer growth. The results strongly suggest that the residual biaxial strain caused by the post-growth cooling can be modified by the incorporation of point defects during the main layer growth which introduce an additional hydrostatic strain field. The effect allows for strain engineering of GaN crystals.

1 aKisielowski, Christian, F.1 aKrüger, Joachim1 aLeung, Michael, S.H.1 aKlockenbrink, Ralf1 aFujii, Hiroaki1 aSuski, Tadeusz1 aSubramanya, Sudhir, G.1 aAger, Joel, W.1 aRubin, Michael, D.1 aWeber, Eicke, R.1 aKrüger, Joachim uhttps://facades.lbl.gov/publications/origin-strain-gan-thin-films03007nas a2200217 4500008004100000245013800041210006900179260001200248300001200260490000700272520227100279653003002550653002002580653001102600653002302611653002302634100001902657700002102676700002302697856006902720 1995 eng d00aOptical and Electrochemical Characteristics of Niobium Oxide Films Prepared by Sol-Gel Process and Magnetron Sputtering: A Comparison0 aOptical and Electrochemical Characteristics of Niobium Oxide Fil c08/1996 a285-2960 v403 a

Electrochromic niobia (Nb205) coatings were prepared by the sot-gel spin-coating and d.c. magnetron sputtering techniques. Parameters were investigated for the process fabrication of sol-gel spin coated Nb205 films exhibiting high coloration efficiency comparable with that d.c. magnetron sputtered niobia films. X-ray diffraction studies (XRD) showed that the sot-gel deposited and magnetron sputtered films heat treated at temperatures below 450°C, were amorphous, whereas those heat treated at higher temperatures were slightly crystalline. X-ray photoelectron spectroscopy (XPS) studies showed that the stoichiometry of the films was Nb205. The refractive index and electrochromic coloration were found to depend on the preparation technique. Both films showed low absorption and high transparency in the visible range. We found that the n, k values of the sot-gel deposited films to be lower than for the sputtered films. The n and k values were n = 1.82 and k = 3 × 10−3, and n = 2.28 and k = 4 × 10−3 at 530 urn for sot-gel deposited and sputtered films, respectively. The electrochemical behavior and structural changes were investigated in 1 M LiC104/propylene carbonate solution. Using the electrochemical measurements and X-ray photoelectron spectroscopy, the probable electrode reaction with the lithiation and delithiation is Nb2O5 + x Li+ + x e ↔ LixNb205. Cyclic voltametric (CV) measurements showed that both Nb205 films exhibits electrochemical reversibility beyond 1200 cycles without change in performance. “In situ” optical measurement revealed that those films exhibit an electrochromic effect in the spectral range 300 < λ < 2100 nm but remain unchanged in the infrared spectral range. The change in visible transmittance was 40% for 250 nm thick electrodes. Spectroelectrochemical measurements showed that spin coated films were essentially electrochemically equivalent to those prepared by d.c. magnetron sputter deposition.

10aD.C. magnetron sputtering10aelectrochromism10aNiobia10aoptical properties10asol-gel deposition1 aÖzer, Nilgün1 aLampert, Carl, M1 aRubin, Michael, D. uhttps://facades.lbl.gov/publications/optical-and-electrochemical02070nas a2200205 4500008004100000245010400041210006900145260002700214520133500241653003201576653002201608653003101630653002601661653002301687653002301710100001901733700002001752700002101772856007101793 1995 eng d00aOptical and Electrochemical Properties of Sol-gel Spin Coated CeO2-TiO2 Films0 aOptical and Electrochemical Properties of Solgel Spin Coated CeO aSan Diego, CAc07/19953 a

The optical and electrochemical properties of sol-gel spin coated Ce02-TiO2 (50% CeO2) films were investigated for electrochrornic applications. The coating solutions were prepared by using mixed organic-inorganic | Ti(OC2H5)4 and Ce(NH4)2 (NO3)6 | precursors. X-ray diffraction studies showed the sol-gel spin-coated films were composed of an amorphous matrix of titanium oxide containing nanocrystallites of cerium oxide. The coating solar transmission value was Ts=0.8 (250 nm thick). The refractive index and the extinction coefficient were derived from transmittance measurements in the UV-VIS-NIR regions. These films had refractive index value of n=2.18 and extinction coefficient value of k=8x10-4 at λ=550 nm. Cyclic voltametric measurements showed reversible electrochemical insertion of lithium ions in a CeO2-TiO2/LiClO4-propylene carbonate electrochemical cell. During cycling the films maintain high optical transmittance. Spectrophotometric and electrochemical investigations performed on CeO2-TiO2 films revealed that these films are suitable as an optically passive counter-electrode in lithium electrochromic devices.

10acerium oxide-titanium oxide10acounter electrode10aelectrochemical properties10aelectrochromic device10aoptical properties10asol-gel deposition1 aÖzer, Nilgün1 aDeSouza, Selmar1 aLampert, Carl, M uhttps://facades.lbl.gov/publications/optical-and-electrochemical-001683nas a2200157 4500008004100000050001400041245009300055210006900148300001200217490000800229520114900237100002301386700002301409700001901432856007401451 1995 eng d aLBL-3804200aOptical Indices of the Tin-doped Indium Oxide and Tungsten Oxide Electrochromic Coatings0 aOptical Indices of the Tindoped Indium Oxide and Tungsten Oxide  a551-5560 v4033 a

Thin films of tin-doped indium oxide are widely used for transparent conductors. One application of In2O3:Sn (ITO) is transparent contacts for electrochromic electrodes. Optical design of electrochromic devices requires knowledge of the optical constants for each layer from the near ultraviolet and visible to the mid infrared. Determination of the optical constants of the electrochromic layer cannot be made in isolation; a complete device or at least a half-cell including a layer of ITO is required to change the optical state of the electrochromic material. Measurements on ITO were made using variable-angle spectral ellipsometry, and spectral transmittance and reflectance. A series of structural models were fit to this data. The problem is complicated because of inhomogeneity in the films, variability in the manufacturing process, and sensitivity to environmental conditions. The spectral dependency was modeled by a single Lorentz oscillator and a Drude free-electron component. This data was then used as the basis for a model to extract the optical constants for a tungsten oxide electrochromic film.

1 avon Rottkay, Klaus1 aRubin, Michael, D.1 aÖzer, Nilgün uhttps://facades.lbl.gov/publications/optical-indices-tin-doped-indium00830nas a2200121 4500008004100000050001400041245007500055210006900130260002900199520037900228100002800607856007300635 1993 eng d aLBL-3503600aOffice Lighting: A Review of 80 Years of Standards and Recommendations0 aOffice Lighting A Review of 80 Years of Standards and Recommenda aToronto, Canadac10/19933 a

This paper traces the development of quantitative office lighting standards from its beginnings to the present. It discusses the sources of recommended lighting practice, the nature of the quantitative recommendations, and trends in recommended values on a comparative basis. A critical assessment of contemporary standards is provided within this historical context.

1 aOsterhaus, Werner, K.E. uhttps://facades.lbl.gov/publications/office-lighting-review-80-years01372nas a2200133 4500008004100000245004500041210004500086260001200131300000900143490000800152520097900160100002101139856007801160 1993 eng d00aOptical Switching Technology for Glazing0 aOptical Switching Technology for Glazing c12/1993 a6-130 v2363 a

The technology of optical switching devices for dynamic glazings and other applications is discussed. The status of the state of the industry and its developments is detailed. The technical emphasis will be on the properties of chromogenic materials covering electrochromic, phase-dispersed liquid crystals and dispersed-particle systems. Such technologies can be used for dynamic control of solar energy through building and vehicle glazings. Both visible and solar control can be obtained from these devices. Switching ranges can be from as high as 80% to 5-10% transmittance in the visible region. The energy and daylighting benefits of such glazings are discussed. Also, chromogenic glazings can be used for other product applications such as the modulation of reflector surfaces and large electronic information display systems. The science of selected electrochromic devices is covered. Technical issues concerning large-scale chromogenic devices are discussed.

1 aLampert, Carl, M uhttps://facades.lbl.gov/publications/optical-switching-technology-glazing01675nas a2200145 4500008004100000050001400041245009100055210006900146260002300215520114400238100002401382700001901406700002501425856007901450 1993 eng d aLBL-3613400aOptimizing the Effective Conductivity and Cost of Gas-Filled Panel Thermal Insulations0 aOptimizing the Effective Conductivity and Cost of GasFilled Pane aTempe, AZc11/19933 a

Gas-Filled Panels, or GFPs, are an advanced theimal insulation that employ a low-conductivity, inert gas, at atmospheiic pressure, within a multilayer reflective baffle. The thermal performance of GFPs varies with gas conductivity, overall panel thickness, and baffle construction. Design parameters of baffle constructions that have a strong effect on GFP thermal resistance are (1) cavities per thickness, (2) cavity surface emittance, and (3) conductance of the baffle materials. GFP thermal performances, where the above parameters were varied, were modeled on a spreadsheet by iterative calculation of one-dimensional energy balances. Heat flow meter apparatus measurements of prototype GFP effective conductivities have been made and are compared to results of the calculations. The costs associated with varying baffle constructions are estimated based on the prices of commercial material components. Results are presented in terms of cost per area per unit thermal resistance ($/Area*R-Value) and are usefid for optimizing GFP designs forsair, argon, or krypton gas fills and a desired effective conductivity and thickness.

1 aGriffith, Brent, T.1 aTurler, Daniel1 aArasteh, Dariush, K. uhttps://facades.lbl.gov/publications/optimizing-effective-conductivity-and